期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 23, 页码 14890-14904出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01539
关键词
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资金
- SERB, New Delhi [CRG/2018/001897(GAP320)]
- ICMR
- CSIR
An efficient method for the generation of uniquely functionalized pyrrolo-pyrrolizinones, pyrido-pyrrolizinones, and azepino-pyrrolizinones via [3 + 2]-dipolar cycloaddition is described. The method involves the synthesis of tethered alkynamides using Ugi condensation and oxidation that were subsequently subjected to a dipolar cycloaddition reaction with trimethylsilyl amino esters. Further transformations to demonstrate the utility of these scaffolds were also investigated.
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