期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 23, 页码 15382-15395出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02188
关键词
-
资金
- National Natural Science Foundation of China [21871035, 21502013]
- Chongqing Research Program of Basic science and Frontier Technology [cstc2019jcyj-msxm2653]
We have developed a convenient synthesis of tetrahydroindolizino[8,7-b]indole derivatives via intramolecular dearomatization of indole. Highly functionalized tetrahydroindolizinoindoles can be prepared in the presence of trifluoromethanesulfonic acid in good to excellent yields (up to >99% yield) with novel designed pyrrole-tethered indoles. The same products can also be synthesized through a mild Fe(OTf)(3)-catalyzed process in acceptable to good yields (up to 75% yield).
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