期刊
ACS APPLIED MATERIALS & INTERFACES
卷 12, 期 45, 页码 50962-50970出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c11677
关键词
urchin-like; alpha-FeOOH; hierarchical structures; anti-oil-fouling performance; crude-oil-in-water emulsions separation
资金
- Key Research and Development Program o f Shandong Province [2019GGX102003]
- Fundamental Research Funds for the Central Universities [20CX05010A]
- PetroChina Innovation Foundation [2019D-5007-0504]
Designing and constructing a stable water-retention layer acting as the isolation between the oil and membrane surface holds great significance for solving the membrane fouling problems in oil/water separation, including common layered oil/water mixtures, immiscible oil-in-water emulsions, and even high-viscosity crude oil-in-water emulsions. Inspired by the self-cleaning property of sea urchin thorns, a bioinspired anti-oil-fouling hierarchically structured membranes decorated with urchin-like alpha-FeOOH particles was successfully prepared via the layer-by-layer (LBL) self-assembly method, maintaining numerous effective micro-nanopores. The hierarchical structured membrane exhibited superior superhydrophilicity/underwater superoleophobicity, high water-retention ability, and preferable anti-oil-fouling properties. Furthermore, the biomimetic membrane with controllable pore sizes could not only separate common layered oil/water mixtures but also effectively separate immiscible surfactant-stabilized oil-in-water emulsions of both low-viscosity crude oil and high-viscosity crude oil with an ultrahigh water flux up to 2598.4 L m(-2) h(-1) and an outstanding separation efficiency of 98.5%, revealing its promising prospect in oily wastewater treatment.
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