期刊
HIGH PERFORMANCE POLYMERS
卷 30, 期 7, 页码 872-886出版社
SAGE PUBLICATIONS LTD
DOI: 10.1177/0954008317734034
关键词
Fluorinated hyperbranched polyimides; monomer synthesis; thermal stability; UV shielding; low dielectric constants
资金
- Natural Science Foundation of Hubei Province, Hubei, China [2013CFB007]
A novel fluorinated aromatic triamine, named 1,3,5-tris (4-(2-trifluoromethyl-4-aminophenoxy)phenyl) benzene (TTFA-POPB), with several -CF3 groups, prolonged chain segments, and ether bonds was first successfully synthesized via a three-step reaction. Then a series of fluorinated hyperbranched polyimides (FHBPIs) with terminal amino or anhydride groups were prepared by condensation polymerization, which were derived from three commercial dianhydrides and the obtained triamine. The prepared FHBPIs showed excellent optical properties with the transmittance reaching 94.5% at 800 nm, favorable ultraviolet (UV)-shielding property with only 27% photodegradation of methylene blue solution after intense UV irradiation for 50 min, good thermal stability with glass transition temperature between 225 degrees C and 264 degrees C, and 10% weight loss temperature of 520-555 degrees C and 509-541 degrees C, respectively, in nitrogen and air atmosphere. They also exhibited relatively good mechanical properties with tensile strength, tensile modulus, and elongation at break values of 64.2-84.2 MPa, 1.2-1.5 GPa, and 6-10%, respectively. Moreover, the introduction of -CF3 and hyperbranched architecture reduced the dielectric constants of the FHBPIs to 2.69-2.92 and increased the surface contact angles to more than 98 degrees. Thus, the FHBPIs are promising dielectric or UV-shielding materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据