期刊
CHEMICAL SCIENCE
卷 11, 期 33, 页码 8793-8799出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc03229h
关键词
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资金
- EPSRC [EP/N01331X/1]
- Spanish Ministerio de Economia, Industria y Competitividad [PGC2018-101464-B-I00]
- [INNVAL 18/28]
- EPSRC [EP/N01331X/1] Funding Source: UKRI
In situsingle-crystal diffraction and spectroscopic techniques have been used to study a previously unreported Cu-framework bis[1-(4-pyridyl)butane-1,3-dione]copper(ii) (CuPyr-I). CuPyr-I was found to exhibit high-pressure and low-temperature phase transitions, piezochromism, negative linear compressibility, and a pressure induced Jahn-Teller switch, where the switching pressure was hydrostatic media dependent.
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