期刊
HELVETICA CHIMICA ACTA
卷 100, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201700059
关键词
Hypervalent iodine; Fluoroalkyl; Thiols; UV absorbance; Coumarins
资金
- ETH Zurich
A new hypervalent iodine reagent (5) based on 1,2-dihydro-3,3-dimethyl-1,2-benziodoxole containing a 4-methyl7-tetrafluoroethoxycoumarin unit as a specific UV absorber was prepared and fully characterized, including X-ray crystal structural analysis. The high reactivity of this compound towards thiols has been exploited for the selective tagging of several targets with the UV chromophore coumarin, including e.g. glutathione.
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