期刊
GREEN CHEMISTRY
卷 19, 期 3, 页码 702-706出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02970a
关键词
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资金
- National Natural Science Foundation of China [21603219, 21422308, 21273231]
- Doctor Startup Foundation of Liaoning Province [20141148]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB17020300]
Depolymerisation of lignin to aromatics is a challenging task. We herein report that a Cu(OAc)(2)/BF3.OEt2 catalyst is effective in simultaneously cleaving C-C bonds in beta-1 and beta-O-4 ketones, yielding esters and phenols. In-depth studies show that C-H bond activation is the rate determining step for C-C bond cleavage. BF3.OEt2 promotes the reaction via activating the beta-C-H bond. This study offers the potential to obtain aromatic esters from lignin.
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