期刊
GREEN CHEMISTRY
卷 19, 期 17, 页码 4169-4175出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc01632h
关键词
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资金
- National Natural Science Foundation of China [21375113, 21573179]
- National Basic Research Program of China [2012CB821600, 2013CB910700]
Commercially available NaOH powder is shown to be an efficient transition-metal-free initiator for the catalytic hydroboration of aldehydes, ketones, alkynes and alkenes with HBpin and 9-BBN under mild conditions. Combined experimental and theoretical studies suggest that the catalytically active species is a boron hydride generated in situ from the reaction mixture.
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