期刊
GREEN CHEMISTRY
卷 19, 期 6, 页码 1490-1493出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc03420a
关键词
-
资金
- National Natural Science Foundation of China [U1504210]
A novel and convenient method has been developed for the 1,2-selenosulfonylation of alkynes under metal-free conditions. The reaction avoids the need for the pre-prepared Se-S reagents, providing facile access to a series of beta-(seleno)vinyl sulfones with high levels of regio- and stereoselectivity. The key features of this reaction include broad substrate scope, excellent functional-group tolerance, readily available reagents and amenability to gram-scale synthesis. Preliminary mechanistic studies support the proposed cationic-species-induced pathway.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据