4.8 Article

A recyclable AgI/OAc- catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

期刊

GREEN CHEMISTRY
卷 19, 期 13, 页码 2936-2940

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc00276a

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资金

  1. State Key Lab of Advanced Technology for Materials Synthesis and Processing
  2. National Science Foundation of China [21502062, 21502146]
  3. Fundamental Research Funds for the Central Universities [WUT: 2017IVA091]

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The cyclization of carbon dioxide and propargylic alcohols, especially challenging substrates, were efficiently catalyzed by a green and recyclable AgI/OAc- system under atmospheric pressure, which is shown to be the most recyclable system with 20 recycle rounds and has the lowest loading among all the reported recyclable systems that work under atmospheric pressure.

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