4.5 Article

Lignocellulosic Fibers from Renewable Resources Using Green Chemistry for a Circular Economy

期刊

GLOBAL CHALLENGES
卷 5, 期 2, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/gch2.202000065

关键词

bamboo; carbonate hydrolysis; green chemistry; hemp; high-kappa kraft pulping; sustainable fibers

资金

  1. State of North Carolina
  2. National Science Foundation [ECCS-1542015]

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The sustainable development of lignocellulose fibers has the potential to replace synthetic polymer feedstocks and generate versatile sustainable products, with research finding that high yield fibers can be obtained using a simple, low-cost, and ecofriendly process. Fibers from different sources exhibit different properties and crystallinity levels.
The sustainable development of lignocellulose fibers exhibits significant potential to supplant synthetic polymer feedstocks and offers a global platform for generating sustainable packaging, bioplastics, sanitary towels, wipes, and related products. The current research explores the dynamics of fiber production from wood, non-wood, and agro-residues using carbonate hydrolysis and a mild kraft process without bleaching agents. With respect to carbonate hydrolysis, high yield, and good coarseness fibers are attained using a simple, low-cost, and ecofriendly process. Fibers produced using a mild kraft process have lower Klason lignin, carboxyl content, surface charges, and higher fiber length, and crystallinity. Eucalyptus fibers show the highest crystallinity while softwood carbonate fibers show the lowest crystallinity. Hemp hurd fibers contain the highest concentration of hard-to-remove water, and thus, suffer maximum flattening visualized by the microscopic images. The relatively high yield sustainable fibers with versatile properties can provide a significant economic benefit since fiber is the dominant cost for producing various bioproducts to meet society's current and future needs.

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