期刊
IONICS
卷 27, 期 1, 页码 49-58出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-020-03812-1
关键词
MOFs; Anode; Lithium-ion battery
资金
- National Natural Science Foundation of China [21875205, 21671168]
- Natural Science Foundation of Hebei [17964403D, 206Z4404G]
By preparing ZnO-CuOx/C composite material, the optimization of lithium-ion battery anode material is achieved, exhibiting excellent pore structure, high specific surface area, excellent conductivity, and abundant active sites, with outstanding lithium storage performance.
Controlling the morphology and pore size is the key to improving the efficiency of electrode materials. In this work, ZnO-CuOx/C, as a lithium-ion anode material, is prepared using ZIF-8@CuO as an initial composite material. The two metal oxides become uniformly distributed on the carbon material, which not only inherits the excellent pore structure and high specific surface area of ZIF-8 but also exhibits excellent conductivity and abundant active sites. Furthermore, ZnO-CuOx/C demonstrates outstanding lithium storage performance. After 500 cycles at a current density of 100 mA g(-1), the capacity remains at a relatively high level of 1061.2 mAh g(-1). After 1000 cycles at a current density of 1000 mA g(-1), the capacity stays as high as 500 mAh g(-1). Therefore, the prepared composite material possesses favourable rate capacity.
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