期刊
ADVANCED FUNCTIONAL MATERIALS
卷 31, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202007129
关键词
direct ethanol fuel cells; energy conversion; high‐ entropy alloys; multicomponent electrocatalysts; solid‐ state device
类别
资金
- National Natural Science Foundation of China [51702031, 51871077, 61974082]
- Shenzhen Fundamental Research Program [JCYJ20180306171644942, JCYJ20180507184623297, KQJSCX20180328165656256]
- Harbin Institute of Technology
A generic dealloying procedure was reported to synthesize nanoporous multicomponent anodic and cathodic catalysts for high-performance ethanol fuel cells. The flexible solid-state ethanol fuel cell demonstrated outstanding energy density with high flexibility, durability, and an inject-and-run function. The use of high-entropy alloy and dealloyed spinel nanosheets as catalysts contributed to the impressive performance of the fuel cell.
As in many other electrochemical energy-converting systems, the flexible direct ethanol fuel cells rely heavily on high-performance catalysts with low noble metal contents and high tolerance to poisoning. In this work, a generic dealloying procedure to synthesize nanoporous multicomponent anodic and cathodic catalysts for the high-performance ethanol fuel cells is reported. On the anode side, the nanoporous AlPdNiCuMo high-entropy alloy exhibits an electrochemically active surface area of 88.53 m(2) g(Pd)(-1) and a mass activity of 2.67 A mg(Pd)(-1) for the ethanol oxidation reaction. On the cathode side, the dealloyed spinel (AlMnCo)(3)O-4 nanosheets with no noble metals demonstrate a comparable catalytic performance as the standard Pt/C for the oxygen reduction reaction, and tolerance to high concentrations of ethanol. Equipped with such anodic and cathodic catalysts, the flexible solid-state ethanol fuel cell is able to deliver an ultra-high energy density of 13.63 mWh cm(-2) with only 3 mL ethanol, which is outstanding compared with other similar solid-state energy devices. Moreover, the solid-state ethanol fuel cell is highly flexible, durable and exhibits an inject-and-run function.
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