期刊
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
卷 18, 期 6, 页码 1289-1302出版社
SPRINGER
DOI: 10.1007/s13738-020-02110-x
关键词
Morphology; LiMn2O4; Nanocomposite; Hydrothermal
In this study, beta- MnO2 and gamma- MnO2 with different morphologies were synthesized by a simple hydrothermal method, and then converted to LMO through a solid-state reaction. It was found that the nanorod-decorated LMO composite exhibited excellent discharge capacity and cycling stability at high current density.
In the present work, beta- MnO2 with the morphology of stacked nanowire-decorated nanorods and gamma- MnO2 with morphology of nanosheets have been prepared by a simple and new one-step hydrothermal method without the application of any surfactants or templates. Then, the MnO2 nanostructures converted to the LiMn2O4 (LMO) with solid-state reaction. RGO and LMO/RGO nanocomposites were successfully synthesized and characterized using FT-IR, XRD, EDS, and SEM methods. The lithiation/delithiation electrochemical behaviors of nanocomposites were investigated employing electrochemical galvanostatic charge-discharge and electrochemical impedance spectroscopy. The nanorod-decorated LMO composite delivered the highest discharge capacitance of 141 mAh g(-1) at 700 mA g(-1) current density, with the capacity retention as high as 92% observed after 50 cycles.
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