期刊
SOFT MATTER
卷 17, 期 1, 页码 113-119出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sm01804j
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资金
- CSIR, India
- UGC, India
A series of discotic tripeptides containing a rigid aromatic core and L-phenylalanine have been developed, and their aggregation properties were found to be strongly influenced by the orientation of the amide bonds. The study revealed differences in the aggregation properties and morphology of the discotic tripeptides, with C-3-symmetric peptides forming organogels and N-centered and C=O-centered peptides forming 3-fold intermolecular H-bonded helical columns. This research provides a valuable approach for fine-tuning functional materials based on discotic tripeptides.
A series of discotic tripeptides containing a rigid aromatic core and l-phenylalanine have been developed. The orientation of the amide bonds yielded variations of the structure and self-assembly properties of the compounds. The aggregation behavior of the discotic tripeptides was studied by various spectroscopic techniques. The morphology of the resulting aggregates was studied by field emission electron microscopy and atomic force microscopy. These studies showed that the orientation of the amide bonds has a strong influence on the intermolecular interactions, resulting in huge differences in the aggregation properties, and morphology of the discotic tripeptides. Only the C-3-symmetric discotic tripeptides formed organogels. The supramolecular aggregation mechanism of N-centered and C=O-centered discotic tripeptides for forming 3-fold intermolecular H-bonded helical column were the same, there was only a smaller enthalpy change due to the occurrence of longer distances for the N-H center dot center dot center dot C bonds of the N-centered discotic tripeptide. Whereas, the C-2-symmetric discotic tripeptides 2 and 3 adopted a 6-fold intermolecular H-bonded dimer structure. Thus, this report presents a valuable approach for the fine-tuning of the discotic tripeptide based functional material.
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