期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 168, 期 1, 页码 -出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/abd44a
关键词
Siloxene; Germanane; Batteries Li-ion; Electrochemical Mechanism
资金
- French National Research Agency (STORE-EX Labex Project) [ANR-10-LABX-76-01]
The study found that layered siloxene and germanane as anodes for lithium-ion batteries exhibit excellent performance, mainly due to their layered morphology that buffers volume changes and improves kinetics. The lithiation pathways of siloxene and germanane are slightly different than silicon and germanium, resulting in different lithiated intermediates.
The layered siloxene and germanane, derived from CaSi2 and CaGe2, respectively, have shown very promising results as anodes for Lithium-ion batteries. Their delivered capacities, capacity retention and high rate cycling are superior compared to bulk Si and Ge. These positive features are most probably related to the layered morphology that buffers the volume changes and improves the kinetics. Despite numerous recently published studies regarding their electrochemical properties, very little is known about their electrochemical mechanism. In this work, we have used a combination of different characterization techniques to study the processes taking place during the lithiation of siloxene and germanane and compared with Si and Ge. Our results suggest a slightly different pathway for the lithiation of siloxene and germanane: their initial layered morphology is preserved after cycling, the crystalline Li15Si4 and Li15Ge4 characteristic of an alloying mechanism are absent and possibly different lithiated intermediates are formed. We provide then, an initial assessment of the involved LixSi and LixGe phases and propose the hypothesis of a reversible Li intercalation in the siloxene and germanane layers.
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