Controllable synthesis of non-layered two-dimensional plate-like CuGaSe2 materials for optoelectronic devices

CuGaSe2 semiconductor materials, as an important member of the I-III-VI2 family, have sparked tremendous attention due to their fascinating structure-related properties and promising applications in solar energy storage and conversion. Nevertheless, the controllable preparation of two-dimensional (2D) CuGaSe2 structures is still a daunting challenge owing to the intrinsic non-layered crystal structure and inaccessible reactivity-matching of multiple reaction precursors, which will seriously impede the much deeper research progress on their properties and applications. Herein, non-layered 2D CuGaSe2 plates possessing high crystallinity, and uniform size and morphology have been first synthesized by a feasible cation exchange strategy. Because the fabrication of 2D CuGaSe2 crystals is rarely reported, a particular highlight is laid on the compositional analysis, structural characterization, and formation mechanism. Furthermore, the optical absorption and optoelectronic measurements reveal that the as-synthesized CuGaSe2 plates exhibit high light harvesting capacity and excellent photoelectric performance. This study opens up a new avenue for the feasible fabrication of non-layered CuGaSe2 plates possessing a high-quality crystalline structure and provides a promising candidate for the development of novel solar energy conversion and storage devices.

Automated summary

The synthesis of high-quality crystalline non-layered CuGaSe2 plates has been achieved through a feasible cation exchange strategy, overcoming the challenging obstacles and providing a promising candidate for the development of novel solar energy conversion and storage devices. This study opens up new possibilities for the production of advanced semiconductor materials with high efficiency and performance.