期刊
NANOSCALE
卷 13, 期 2, 页码 1213-1219出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nr05941b
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资金
- National Natural Science Foundation of China [21838003, 21676093, 21776092, 21808061, 91834301]
- Shanghai Scientific and Technological Innovation Project [18JC1410500]
- Social Development Program of Shanghai [17DZ1200900]
- Innovation Program of Shanghai Municipal Education Commission
- Fundamental Research Funds for the Central Universities [222201718002]
- Australian Research Council (ARC) [FL160100089]
This study demonstrates the possibility of enhancing the electrochemical activity of MOF-derived binary metal center catalysts by controlling the form of Fe species, introducing Fe-SBU can improve electroconductivity and reduce the overpotential of the OER reaction.
Restricting the aggregation and rationally adjusting the electronic structure of binary metal centers in metal-organic framework (MOF) precursors are important for optimizing their performance as electrocatalysts for the oxygen evolution reaction (OER) and achieving low overpotential and high stability in such applications. Herein, we demonstrate the possibility of enhancing the electrochemical activity of MOF-derived binary metal center catalysts by controlling the form of the Fe species. The introduction of Fe-SBU (iron 2,5-dihydroxyterephthalic acid) into ZIF-67 is found to induce a distinct confinement effect and this can be exploited to improve the electroconductivity of binary metal center catalysts, and therefore, to reduce the OER reaction barrier (OOH* -> O*). When applied as an OER catalyst in 1 M KOH solution, the Fe-SBU@Co-Matrix catalyst exhibits a low overpotential of 249 mV to reach a current density of 10 mA cm(-2) and high stability for over 40 h. This work describes the secondary growth treatment of MOF-derived porous carbons to promote their application as catalysts in energy conversion reactions.
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