期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 17, 页码 2132-2135出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00240f
关键词
-
资金
- Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences [RVO: 613 88963]
- Czech Science Foundation [20-13745S, 20-01472S]
- Ministry of Education, Youth and Sports [LTAUSA19120]
- US National Science Foundation [CHE-1905238]
Solvent-free mechanochemical synthesis was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules. Confirmation of successful formation of individual inclusions was independently confirmed by solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis is an alternative route towards new types of cucurbit[n]uril-guest inclusion complexes.
Solvent-free mechanochemical synthesis (ball-milling) was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules (adamantane, adamantyl-1-amine hydrochloride, toluidine hydrochloride, and p-phenylenediamine dihydrochloride). Successful formation of individual inclusions was independently confirmed by one- and two-dimensional solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis represents an alternative path towards new types of cucurbit[n]uriliguest inclusion complexes that are not accessible due to limited solubility of the individual components.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据