期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 10, 页码 1218-1221出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05570k
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资金
- National Natural Science Foundation of China [21671080]
- Project of Shandong Province Higher Educational Science and Technology Program [J18kz005]
- Young Innovative Talents Introduction & Cultivation Program for Colleges and Universities of Shandong Province: Innovative Research Team on Optoelectronic Functional Materials
A new type of hybrid lead halide compound, [DTHPE](2)Pb3Cl10, with a one-dimensional chain structure based on a corner-shared [Pb3Cl11] cluster has been synthesized. This cluster-based 1D chain exhibits intrinsic broadband white light emission with a high quantum efficiency of 19.45%, surpassing that of typical two-dimensional perovskites reported previously.
One new type of hybrid lead halide of [DTHPE](2)Pb3Cl10 has been synthesized and characterized containing a one-dimensional (1D) wavelike [Pb3Cl10](4-) chain based on a corner-shared [Pb3Cl11] cluster. Remarkably, this cluster-based 1D chain displays intrinsic broadband white light emission with a high quantum efficiency of 19.45% exceeding those of previously reported typical two-dimensional perovskites.
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