4.8 Review

Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

期刊

GREEN CHEMISTRY
卷 23, 期 3, 页码 1077-1113

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc03824e

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资金

  1. CERCA Program/Generalitat de Catalunya, ICREA
  2. Spanish MINECO [CTQ2017-88920-P]
  3. AGAUR [2017-SGR-232]
  4. Ministerio de Ciencia e Innovacion [CEX2019-000925-S]
  5. European Community [889754, 840557]
  6. Thailand Research Fund [RSA6080059]
  7. Marie Curie Actions (MSCA) [840557, 889754] Funding Source: Marie Curie Actions (MSCA)

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Biomass-related feedstock can be used as a coupling partner with CO2, allowing the development of more functional and complex carbonate architectures. This development has become an important part of new and more sustainable material designs in recent years.
Cyclic organic carbonates are among the most widely studied targets in the nonreductive conversion of carbon dioxide using oxiranes as the common reaction partners. Apart from using fossil fuel based precursors, recent developments have shown that biomass related feedstock can also serve as coupling partner for CO2 allowing the preparation of more functional and complex types of carbonate architectures. This tutorial review places this latter development in the current context of new and more sustainable material designs, and highlights the main types of biomass that have been examined using primarily homogeneous catalysis approaches.

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