4.7 Article

Effect of reactant sequence on the structure and properties of self-assembled TiO2 microspheres with exposed {001} surfaces

期刊

CRYSTENGCOMM
卷 23, 期 3, 页码 724-729

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ce01515f

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资金

  1. Tianjin Natural Science Foundation [18JCYBJC87600]
  2. Natural Science of Tianjin Municipal Education Commission Scientific Research Project [2017KJ052]

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Highly exposed {001} surfaces of ITD-TiO2 and IDT-TiO2 microspheres were prepared through an intermittent two-step hydrothermal method, showing excellent photocatalytic activity compared to P25. IDT-TiO2 exhibited a significant increase in surface photovoltage, indicating more carriers can be generated during the photocatalytic process. The order of adding the titanium source and morphology control agent was found to be a key factor influencing the morphology of the sample in this research system.
Highly exposed {001} surfaces of ITD-TiO2 and IDT-TiO2 microspheres with a self-assembled hierarchical structure were prepared via an intermittent two-step hydrothermal method. ITD-TiO2 possesses a polycrystalline structure, and the particle size is about 500 nm. The specific surface area of ITD-TiO2 was found to be 199.21 m(2) g(-1), which is significantly larger than that of P25. ITD-TiO2 exhibited excellent photocatalytic activity; the degradation rate of MO reached 99.0% after UV-light irradiation for 3.0 h and is 63.6% higher than that of P25. The surface photovoltage of IDT-TiO2 heat-treated at 500 degrees C was 264 mu V, which indicates that more carriers can be generated inside the sample during the photocatalytic process. Moreover, the order of adding the titanium source and morphology control agent in this research system is the key factor affecting the morphology of the sample. This is mainly because the hydrolysis and nucleation of tetrabutyl titanate in the precursor solution is affected by diethylenetriamine.

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