期刊
HELIYON
卷 7, 期 1, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.heliyon.2021.e06062
关键词
Modified rice husk; Palladium; Preconcentration
The bio-matrix of rice husk was modified and used for preconcentration of Pd2+ prior flame atomic absorption spectrometric determination. The material was characterized and evaluated for its adsorption capacity under different parameters, achieving a maximum capacity at optimum conditions. The method showed good detection limits and dynamic analytical range, with the sorbent capable of regeneration for multiple cycles without significant reduction in adsorption capacity.
Bio-matrix of rice husk and Mobil Composition of Matter No. 41 (MCM-41) was modified with alizarin red S for preconcentration of Pd2+ prior flame atomic absorption spectrometric determination. The prepared bio-matrix (RH@MCM-41@ARS) was characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope, energy dispersive X-ray spectrometer (SEM/EDX) and surface area studies. The impact of different parameters (solution pH, amount of sorbent, contact time, sample volume, initial Pd2+ concentration and diverse ions) on the uptake of Pd2+ were evaluated. The maximum adsorption capacity of Pd2+ onto RH@MCM-41@ARS was 198.2 mg g(-1) at optimum conditions. Applying the optimized procedure as a preconcentration step led to limit of detection of 0.13 mu g L-1 and dynamic analytical range up to 500 mu g L-1. The sorbent was regenerated by 0.5 mol L-1 thiourea for at least 10 cycles without significant reduction of adsorption capacity. The method was applied for preconcentration of Pd2+ from real samples.
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