4.6 Article

Promoting dry reforming of methane via bifunctional NiO/dolomite catalysts for production of hydrogen-rich syngas

期刊

RSC ADVANCES
卷 11, 期 12, 页码 6667-6681

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra09246k

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资金

  1. Kementerian Pendidikan Tinggi of Long-Term Research Grant Scheme (LRSG) NanoMITE [5526308]
  2. Putra Grant IPS [9643000]
  3. IPM, Universiti Putra Malaysia [9559000]

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Efforts have been made to develop an efficient catalyst for CO2 reforming of CH4 with high activity, cost-effectiveness, and resistance to deactivation. A new bifunctional NiO/dolomite catalyst system showed unique performance in terms of amphoteric sites and self-reduction properties, enhancing CH4 and CO2 conversion without involving a catalyst reduction step.
Extensive effort has been focused on the advancement of an efficient catalyst for CO2 reforming of CH4 to achieve optimum catalytic activity together with cost-effectiveness and high resistance to catalyst deactivation. In this study, for the first time, a new catalytic support/catalyst system of bifunctional NiO/dolomite has been synthesized by a wet impregnation method using low-cost materials, and it shows unique performance in terms of amphoteric sites and self-reduction properties. The catalysts were loaded into a continuous micro-reactor equipped with an online GC-TCD system. The reaction was carried out with a gas mixture consisting of CH4 and CO2 in the ratio of 1 : 1 flowing 30 ml min-1 at 800 degrees C for 10 h. The physicochemical properties of the synthesized catalysts were determined by various methods including X-ray diffraction (XRD), N2 adsorption-desorption, H2 temperature-programmed reduction (H2-TPR), temperature-programmed desorption of CO2 (TPD-CO2), and temperature-programmed desorption of NH3 (TPD-NH3). The highest catalytic performance of the DRM reaction was shown by the 10% NiO/dolomite catalyst (CH4 & CO2 conversion, chi CH4; chi CO2 similar to 98% and H2 selectivity, SH2 = 75%; H2/CO similar to 1 : 1 respectively). Bifunctional properties of amphoteric sites on the catalyst and self-reduction behaviour of the NiO/dolomite catalyst improved dry reforming of the CH4 process by enhancing CH4 and CO2 conversion without involving a catalyst reduction step, and the catalyst was constantly active for more than 10 h.

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