期刊
CHEMICAL PAPERS
卷 75, 期 7, 页码 3103-3118出版社
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s11696-021-01540-y
关键词
Kinetics; [BTB](keto); Physical vapor deposition; DFT; FTIR; Optical properties
资金
- Chemistry Department, Faculty of Science, New Valley University, El-Kharga, New Valley, Egypt
A crystalline [BTB](Keto) was successfully synthesized in different media at 25 degrees C based on an oxidation method in the presence of potassium permanganate. The redox reactions occur in alkaline and acidic media, with distinct stages observed in alkaline medium and a single stage in acidic medium. The resulting dye particles and thin films show promising potential for applications in optoelectronics and solar cells based on various characterization techniques.
A crystalline ((3-bromo-5-isopropyl-2-methyl-4-oxocyclohxa-2,5-dien-1-yl)methyl 4MODIFIER LETTER PRIME-hydroxy-5MODIFIER LETTER PRIME-isopropyl-2MODIFIER LETTER PRIME-methyl-[1,1MODIFIER LETTER PRIMEbiphenyl]-2-sulfonate) [BTB](Keto) was synthesized in different media at 25 degrees C based on an oxidation method in the presence of potassium permanganate. The redox reactions occur in alkaline and acidic media. In alkaline medium, two distinct stages were observed: The first stage was relatively fast and the second stage was relatively slow. The first step coexists with the formation of intermediate complexes involving transient species relatively quickly of the blue hypomanganate (V) and green manganate (VI). The slowly decomposed intermediate formed to produce soluble colloidal manganese (IV) and the BTB keto-derivatives as second slow-stage oxidation products. But in acidic medium, oxidation reaction occurs in one stage because the first stage was found to be very fast and cannot be followed and the second stage was found to be slow so the reaction occurs in one stage (slow stage) to give rise to the final oxidation product [BTB](Keto). Thin films were produced through physical vapor deposition. Both the resulting dye particles and prepared thin films were deeply discussed using various techniques including Fourier transform infrared (FTIR), X-ray diffraction (XRD), ultraviolet-visible spectroscopy (UV-Vis), and optical properties. DMol(3) and Cambridge Serial Total Energy Package (CASTEP) program performed the optimization of the samples using density functional theory (DFT). An XRD and FT-IR study established the structural properties of the resultant dye. The XRD tests of thin films (monoclinic 2) display crystal structure. An optical measurement found that with growing photon energy the optical constants (refractive index n, absorption index k, dielectric constants, and optical conductivity) decreased. The optical properties of the dye thin films found in model FTIR, XRD, and CATSTEP are in strong alignment with the experimental research. The dye thin films show a compelling outcome to be a successful choice for applications in optoelectronics and solar cells. [GRAPHICS] .
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