期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 9, 期 6, 页码 1888-1894出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0tc04697c
关键词
-
资金
- Israel Science Foundation [488/16]
Theoretical studies have traditionally focused on ion migration within the perovskite layer, but emerging experimental evidence suggests ions can also migrate into blocking layers, impacting device degradation. Simulation results show good agreement with experimental data, indicating ion accumulation at the electrode interface as a key factor in device dynamics. Additionally, migration into blocking layers is found to significantly influence the device energy level diagram and can potentially alter the perovskites into p or n type solar cells.
Theoretical studies of ion migration have thus far focused on migration within the perovskite layer only. This reflected a hidden'' assumption that the electron/hole blocking layers also function as ion blocking. Following experimental evidence, we study the effect of ion migration into the blocking layers and as a case study we compare our simulations to experimental results of device degradation under storage conditions (V = 0, dark), obtained by others. Good agreement is found between the simulated ion accumulation at the electrode interface with the experimental device degradation dynamics. Also, we find that the migration into the blocking layers dominates the effects on the device energy level diagram and that it may also turn the intrinsic perovskites into either p or n type solar cells. Although our simulations do not include the chemistry of degradation, they show two potential mechanisms associated with ion out-diffusion. First, the electron/hole balanced solar cell structure becomes imbalanced (should be reversible). Second, ions reaching the electrode may react with it (i.e. irreversible).
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