4.7 Article

Low-temperature dry reforming of methane to produce syngas in an electric field over La-doped Ni/ZrO2 catalysts

期刊

FUEL PROCESSING TECHNOLOGY
卷 158, 期 -, 页码 96-103

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.fuproc.2016.11.013

关键词

Dry reforming of methane; Carbon dioxide utilization; Electric field; Low temperature catalytic reaction; Low carbon deposition

资金

  1. Leading Graduate Program in Science and Engineering, Waseda University from MEXT, Japan
  2. Grants-in-Aid for Scientific Research [26289306] Funding Source: KAKEN

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Dry reforming of methane (DRM) was conducted over various transition metal supported ZrO2 catalysts in an electric field. Catalyst of lwt%Ni/10 mol%La-ZrO2 showed high DRM activity even at 423 K of external temperature, at which no DRM proceeds in the conventional catalytic systems. By virtue of the low reaction temperature, low amounts of carbon deposition were confirmed even in conditions of high CH4 conversion in the electric field. The imposed electric power was correlated to with the catalytic activities in the electric field. Syngas is producible at low temperature with high energy efficiency. (C) 2016 Elsevier B.V. All rights reserved.

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