4.7 Article

Visible-light promoted α-alkylation of glycine derivatives with alkyl boronic acids

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CHEMICAL COMMUNICATIONS
卷 57, 期 15, 页码 1959-1962

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07688k

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  1. National Natural Science Foundation of China [21961033]

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This method utilizes a visible-light-mediated aerobic alpha-alkylation reaction of glycine derivatives with alkyl boronic acids in the presence of a Ru/Cu catalyst system to efficiently produce a wide range of complex unnatural alpha-amino-acid derivatives. It features mild reaction conditions and broad substrate scope.
A visible-light-mediated aerobic alpha-alkylation reaction of glycine derivatives with alkyl boronic acids has been established in the presence of a Ru/Cu catalyst system, giving the desired radical coupling products efficiently. The transformation features mild reaction conditions and broad substrate scope, delivering a wide range of complex unnatural alpha-amino-acid derivatives.

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