期刊
FUEL
卷 189, 期 -, 页码 419-427出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2016.10.122
关键词
Methanation; Ni-based catalyst; Stability
资金
- National Natural Science Foundation of China [51476034, 51525601]
- Natural Science Foundation of Jiangsu Province [BK20161423]
Methanation of syngas (H-2/CO) in a fixed-bed down-flow reactor under atmospheric atmosphere was investigated over a series of Ni-based catalysts with Fe and TiO2 as the support. The prepared catalysts (Ni/Al2O3, Ni-Fe/Al2O3, and Ni-Fe/TiO2-Al2O3) were characterized by N-2 adsorption-desorption, X-ray diffraction (XRD), temperature-programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS). The characteristics of the catalysts for the methanation process were investigated with the ratio of H-2/CO as 3: 1 under an atmospheric pressure. The addition of Fe in the Ni/Al2O3 catalyst could promote the dispersion of Ni species and decrease the reduction temperature of catalyst. The optimal ratio for Ni-Fe/Al2O3 catalyst was estimated to be 1 due to the small-sized Ni particles and easily reducible beta-type NiO species, giving the CO conversion of 97% and CH4 selectivity of 94% at 262 degrees C. The addition of TiO2 (10 wt%) in Ni-Fe/Al2O3 catalyst promotes the formation of Ni-Fe alloy, facilitating the methanation reaction at low temperatures and suppressing the coke deposition. This also results in the outstanding stability of the Ni-Fe/TiO2-Al2O3 catalyst over other Ni-Fe/Al2O3 catalysts. (C) 2016 Elsevier Ltd. All rights reserved.
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