4.6 Article

Selective Area Regrowth Produces Nonuniform Mg Doping Profiles in Nonplanar GaN p-n Junctions

期刊

ACS APPLIED ELECTRONIC MATERIALS
卷 3, 期 2, 页码 704-710

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.0c00863

关键词

gallium nitride; p-n junction; selective area doping; selective area regrowth; atom probe tomography; dopant profiling

资金

  1. Advanced Research Projects Agency-Energy (ARPA-E), U.S. Department of Energy as part of the PNDIODES program [DE-AR0000871]
  2. National Science Foundation's MRSEC Program [DMR-1121262]
  3. Initiative for Sustainability and Energy at Northwestern (ISEN)
  4. Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource [ECCS-1542205]
  5. MRSEC program at the Materials Research Center [NSF DMR-1121262]
  6. International Institute for Nanotechnology (IIN)
  7. Keck Foundation
  8. State of Illinois through the IIN

向作者/读者索取更多资源

Nonplanar GaN p-n junctions formed by selective area regrowth were studied using pulsed laser atom probe tomography. Results showed that Mg dopant concentration varies inversely with growth rate and negligible growth on vertical sidewalls, with high Mg concentration attributed to etching damage near regrowth interfaces. Further research is needed on growth conditions to reduce variations in growth rate and nonuniform doping in device fabrication processes.
Nonplanar GaN p-n junctions formed by selective area regrowth were analyzed using pulsed laser atom probe tomography. Dilute Al marker layers were used to map the evolution of the p-GaN growth interface, enabling extraction of time-varying growth rates for nonpolar, semipolar, and polar surfaces from the trench edge to the center, respectively. The Mg dopant concentration is facet-dependent and varies inversely with the growth rate for the semipolar facets that grow rapidly away from the trench sidewalls. The negligible growth on the vertical sidewall of the trench coincides with an order of magnitude higher Mg concentration and substantial clustering of likely inactive dopants. A high Mg concentration is also observed near the regrowth interface of polar and semipolar planes, which we attribute to etching damage. We conclude that device fabrication processes employing selective area regrowth on nonplanar interfaces should consider both the spatial and temporal dependencies of growth rate that lead to nonuniform doping and explore growth conditions that could reduce variations in growth rate when nonuniform doping would adversely affect device performance.

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