期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 19, 期 7, 页码 1438-1458出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ob02309d
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资金
- DoP, India
- National Institute of Pharmaceutical Education and Research (NIPER), Hyderabad
- DST-Inspire faculty
- NIPER-Hyderabad
- Department of Science & Technology- Inspire Faculty [DST/INSPIRE/04/2018/001660]
- NIPER Hyderabad
In the past two decades, transition metal-catalyzed C-H functionalization followed by annulations with various coupling partners has attracted much attention in organic synthesis. Rh(iii) or Ir(iii) catalyzed regioselective C-H functionalization followed by the cyclization of diverse arenes with metal carbene precursors has become a highly investigated research field recently. This review aims to provide a comprehensive essay on the Rh(iii)/Ir(iii) catalyzed C-H functionalizations/annulations via carbene migratory insertion, with a focus on diverse metal carbene precursors with arenes/alkenes reported so far.
In the past two decades, transition metal-catalyzed C-H functionalization followed by annulations with various coupling partners has received much attention in organic synthesis. In particular, Rh(iii) or Ir(iii) catalyzed regioselective C-H functionalization followed by the cyclization of diverse arenes with metal carbene precursors has become a highly investigated research field in recent years. The purpose of this review is to provide a comprehensive essay on the Rh(iii)/Ir(iii) catalyzed C-H functionalizations/annulations via carbene migratory insertion, focusing on the diverse metal carbene precursors with arenes/alkenes reported so far. The highlighted examples are categorized by nitrogen, oxygen, sulfur-containing heterocycles and carbocyclizations. Further, key mechanistic approaches are also briefly described.
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