期刊
DALTON TRANSACTIONS
卷 50, 期 7, 页码 2350-2353出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt04149a
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资金
- EPSRC [EP/J015156/1, EP/L023652/1, EP/I033459/1, EP/K023004/1]
- ERC [670467 SMART-POM]
- China Scholarship Council
- National Natural Science Foundation of China [21901016]
- EPSRC [EP/L023652/1, EP/I033459/1, EP/R020914/1, EP/J015156/1, EP/K023004/1] Funding Source: UKRI
A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The intramolecular paramagnetic interactions between TEMPO radicals and Mn ions were studied in detail using electron paramagnetic resonance and Evans NMR methods.
A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The complexes were structurally characterised by single crystal X-ray diffraction and the intramolecular paramagnetic interactions between TEMPO radicals and Mn ions of the resulting hybrids were investigated in detail by electron paramagnetic resonance and the Evans NMR method.
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