期刊
RSC ADVANCES
卷 11, 期 14, 页码 7972-7980出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra00329a
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资金
- JSPS
- MEXT
The compound 2,3-dimethoxy-2,3-dimethyl-1,4-dioxane serves as a stable precursor to functionalized cyclohexene derivatives through a [4+2] cycloaddition reaction, which can be transformed into potentially useful intermediates for biologically important materials.
2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane readily prepared from biacetyl serves as a stable precursor to 2,3-dimethylene-1,4-dioxane which undergoes a [4+2] cycloaddition reaction with dienophiles to give functionalized cyclohexene derivatives. The cycloaddition adducts obtained by the present procedure are transformed into potentially useful intermediates for biologically important materials.
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