期刊
GREEN CHEMISTRY
卷 23, 期 5, 页码 2169-2176出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc00227a
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资金
- National Key R&D Program of China [2018YFB1501502]
- National Natural Science Foundation of China [21875239]
- Fundamental Research Funds for the Central Universities [WK3530000004]
A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate, with a 92% yield achieved through tandem benzoin condensation and hydrodeoxygenation reaction. The effects of reaction factors were investigated in detail, and the hydrodeoxygenation process was explored using H-1-NMR and GC-MS analysis.
A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate. 92% yield of the acetates was obtained through the tandem benzoin condensation and hydrodeoxygenation reaction. During the benzoin condensation, furfural was catalyzed into furoin in a quantitative yield by the immobilized NHC catalyst under solvent-free conditions. After dissolving the furoin intermediate in acetic acid, the Sc(OTf)(3) and Pd/C catalytic system was introduced for hydrodeoxygenation. The effects of reaction factors have been investigated in detail and the hydrodeoxygenation process has been explored by H-1-NMR and GC-MS.
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