4.8 Review

Supramolecular self-assembly of nucleotide-metal coordination complexes: From simple molecules to nanomaterials

期刊

COORDINATION CHEMISTRY REVIEWS
卷 292, 期 -, 页码 107-143

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.02.007

关键词

Chirality; Functional nanomaterials; Nucleotide-metal coordination complexes; Single crystal structure; Supramolecular assembly

资金

  1. National Science Council of the People's Republic of China [20771014, 21071018, 21271026]
  2. Specialized Research Fund for the Doctoral Program of Higher Education, State Education Ministry of China [20091101110038]

向作者/读者索取更多资源

Nucleotides are essential components of DNA and RNA, and their functions depend mainly on the participation of metal ions. Thus, research into nucleotide-metal coordination complexes, including the affinities of different coordination donors for metal ions, molecular and crystal structures, supramolecular assembly, and functional nanoparticles, will contribute to the interdisciplinary field of chemistry,biology, and materials. Numerous achievements have been reported in this area but few comprehensive reviews have considered nucleotide-metal complexes from the viewpoints of crystallography and supramolecular chemistry, or aspects of their chirality and chirality delivery. In this review, we describe the coordination ability of nucleotide ligands, the structures and properties of nucleotide-metal coordination complexes, and supramolecular assemblies. We review mononuclear complexes, multinuclear complexes, 1D and 2D coordination polymers, and 3D supramolecular assemblies in terms of their structures, mainly based on their X-ray single crystal diffraction data. In particular, we highlight the chirality of nucleotide-metal complex, including their molecular chirality, supramolecular helical chirality, and extended axial chirality. Furthermore, we summarize the functional properties of nucleotide-metal nano-materials, such as their luminescence, magnetism, and adaptive inclusion properties. We discuss the future challenges and opportunities of research into nucleotide-metal complex. (C) 2015 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据