期刊
COORDINATION CHEMISTRY REVIEWS
卷 304, 期 -, 页码 3-19出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.03.014
关键词
Hydrogen; Cobalt; Polypyridyl ligands; Electrocatalytic activity; Photocatalytic activity
资金
- COST Action CM1202 PERSPECT-H2O
- French National Research Agency (Labex program, ARCANE) [ANR-11-LABX-0003-01]
- FCH Joint Undertaking (ArtipHyction Project) [303435]
- European Research Council under the European Union's Seventh Framework Program (FP)/ERC Grant [306398]
- Life Science Division of CEA (DSV-Energy program)
The search for efficient noble metal-free hydrogen-evolving catalysts is the subject of intense research activity. A new family of molecular cobalt(II)-polypyridyl catalysts has recently emerged. These catalysts prove more robust under reductive conditions than other cobalt-based systems and display high activities under fully aqueous conditions. This review discusses the design, characterization, and evaluation of these catalysts for electrocatalytic and light-driven hydrogen production. Mechanistic considerations are addressed and structure-catalytic activity relationships identified in order to guide the future design of more efficient catalytic systems. (C) 2015 Elsevier B.V. All rights reserved.
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