期刊
COORDINATION CHEMISTRY REVIEWS
卷 304, 期 -, 页码 55-72出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2014.11.006
关键词
Hydrogen production; Solar energy; Re(I) diimine complexes; Homogeneous catalysis; Supramolecular Re compounds
资金
- European Union (European Social Fund-ESF)
- Greek national funds through the Operational Program Education and Lifelong Learning of the National Strategic Reference Framework (NSRF) - Research Funding Program: Thales
- Special Research Account of NKUA
- COST action CM1202 PERSPECT H2O
This review is focused on the photocatalytic properties of the Re(I) compounds in the reduction of H+ and their use in solar energy conversion. Different systems are discussed in terms of the photosensitizer - usually containing the core [ReX(CO)(3)diimine](+) - and mechanistic details are provided. The effect of the axial ligand and coordination of solvent water or TEOA on hydrogen evolution rates is also discussed. Supramolecular systems that mimic enzymes by combining both the photsenzitizer and the catalyst are also presented. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据