Visible-light-induced silylation: an update

Visible-light-driven functionalization of various organic systems has proved to be extremely successful and reached an impressive level of sophistication as well as efficiency in the last two decades. At the same time, organosilicon compounds are significant due to their promising applications in therapeutic agents, drug delivery, building blocks and so on. More interestingly, they are cheap, operationally simple, highly stable, less toxic and easy to handle. In this scenario, an environment-friendly synthetic approach for silylation, such as visible-light-induced silylation, is in high demand at present for molecule construction having the C-Si bond. This perspective summarizes the recent findings and developments in the emerging area of photocatalytic silylation with literature coverage mainly extending from 2014 to February 2021.

Automated summary

Over the past two decades, visible-light-driven functionalization of various organic systems has achieved great success, reaching impressive levels of complexity and efficiency. Organosilicon compounds are significant due to their promising applications in various fields and they are known for being cheap, easily handled, highly stable, and less toxic. Therefore, there is now a high demand for environmentally friendly synthetic approaches, such as visible-light-induced silylation, for molecule construction with C-Si bonds.