期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 19, 期 16, 页码 3634-3643出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob00066g
关键词
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资金
- Department of Science and Technology (DST) India [DST-SB/EMEQ-257/2014]
- CSIR, New Delhi
- DST-Inspire fellowship
- UGC-SRF
- AcSIR [IICT/Pubs./2020/341]
Efficient gold-catalyzed formation of indenylidene-derived 1H-isochromene-4-carbaldehydes from substituted 1,5,10-triyne-O-silanes was achieved under mild reaction conditions. The reaction involved gold-catalyzed selective oxidation, 1,2-migration, nucleophilic addition, and 5-endo-dig cyclization, leading to the synthesis of the desired products in moderate to very good yields via the formation of new C-C and C-O bonds in one pot.
An efficient gold-catalyzed formation of indenylidene-derived 1H-isochromene-4-carbaldehydes from substituted 1,5,10-triyne-O-silanes was developed under mild reaction conditions. In this reaction, gold-catalyzed selective oxidation, 1,2-migration, nucleophilic addition and then 5-endo-dig cyclization took place regioselectively. The indenylidene-derived isochromene-4-carbaldehydes were synthesized in moderate to very good yields via the formation of new C-C and C-O bonds in one pot.
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