4.7 Article

[Bi6Mo3(CO)9]4-: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism

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CHEMICAL COMMUNICATIONS
卷 57, 期 30, 页码 3656-3659

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00734c

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The first Zintl cluster containing a distorted Bi-6 triangular prism, [Bi6Mo3(CO)(9)](4-), has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local sigma-aromaticity.
The first Zintl cluster containing a distorted Bi-6 triangular prism, [Bi6Mo3(CO)(9)](4-), has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local sigma-aromaticity.

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