期刊
CHEMICAL SOCIETY REVIEWS
卷 50, 期 6, 页码 3677-3689出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00966k
关键词
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资金
- Ministry of Science and Technology of China [2016YFE0132600]
- Henan Center for Outstanding Overseas Scientists [GZS2020001]
- Zhengzhou University
Directing group migration has emerged as a practical strategy for transition-metal-catalysed direct C-H activation, leading to highly atom-economical processes and enabling the reusage of directing groups. Progress has been made in developing multitasking directing groups, with the focus on different types of migratable directing groups and their mechanisms, as well as synthetic applications.
Very recently, directing group (DG) migration has emerged as a practical strategy for transition-metal-catalysed direct C-H activation, resulting in a highly atom-economical process and enabling the reusage of DG. Therefore, great progress has been made in developing multitasking DGs. In this tutorial review, we present the rapid advances of this novel strategy by analyzing and comparing the different types of migratabIe DGs (including N-O, N-C, N-N or O-C bond cleavage to trigger DG migration). The related mechanisms, as well as synthetic applications, are also mentioned.
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