期刊
POLYMER CHEMISTRY
卷 12, 期 10, 页码 1393-1403出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0py01389g
关键词
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资金
- NRF of Korea [2020R1A6A3A01096563, 2018R1C1B6003054]
- National Research Foundation of Korea [4199990214002] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Polymer self-assembly using conjugated polymers, known as INCP, offers a simplified method for obtaining stable nano-objects with various morphologies, which have potential applications in optoelectronics. This approach eliminates the need for challenging post-polymerization treatment steps.
Polymer self-assembly is a widely utilized method to prepare a wide range of nano-objects in solution. Typically, preparation of such objects relies on the use of block copolymers and challenging post-polymerization treatment steps. While polymerization induced self-assembly (PISA) can simplify their preparation, the resulting nano-objects typically have poor stability (including sensitivity to solvent, temperature, and mechanical stimuli). An alternative approach is to use conjugated polymers, with a strong driving force for self-assembly, to achieve semiconducting nano-objects. This process is termed in situ nanoparticlization of conjugated polymers (INCP) or PISA using conjugated polymers. With INCP, self-assembled nano-objects can be obtained (without any post-polymerization treatment steps) from block copolymers, using one-pot or one-shot methods, or even homopolymers. Due to the use of conjugated polymers, the nano-objects from INCP have the potential for use in various optoelectronic applications. In this Perspective, we summarize the development of INCP by discussing synthetic methods, accessible nano-objects morphologies, and mechanisms of nano-object formation.
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