期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 12, 页码 5437-5451出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj05921h
关键词
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资金
- University Grants Commission, New Delhi [F.4-2/2006(BSR)/CH/17-18/0105]
- University Grants Commission [F.30-56/2014/BSR]
- Dr Harisingh Gour Vishwavidyalaya (A Central University) Sagar
Distorted octahedral ruthenium(ii) bis-phenanthroline compounds were synthesized and their photochemistry was studied. The photodissociation of N-heterocyclic co-ligands upon blue light irradiation occurred at different rates in different co-ligands, with the first ligand dissociating faster. Density functional theory (DFT) calculations and molecular orbital analysis provided insights into the geometries and energetics of the dissociation process.
Distorted octahedral ruthenium(ii) bis-phenanthroline compounds of the type cis-[Ru(phen)(2)(L)(2)](PF6)(2) (L = isoquinoline 1; phthalazine 2) were synthesized and their photochemistry was investigated. The photodissociation of the monodentate N-heterocyclic co-ligands upon blue light irradiation (lambda(irr) = 470 nm) occurs much more readily in 1 than in 2 with the first ligand dissociating faster than the second ligand. The density functional theory (DFT) calculations were performed to investigate geometries of the (MLCT)-M-3, (TS)-T-3, and dissociative (MC)-M-3 states and the triplet potential energy surfaces. DFT and time-dependent DFT (TD-DFT) calculations reveal a smaller (MLCT)-M-3-(MC)-M-3 energy gap for 1 (0.025 eV) than in 2 (0.090 eV) suggesting the faster dissociation of the first co-ligand in both 1 and 2. On the other hand, the (MLCT)-M-3-(MC)-M-3 energy gap is moderately larger for the monochloro-substituted photoproducts 1a (0.389 eV) and 2a (0.396 eV), leading to the conclusion that the second co-ligand dissociation is slower in both 1a and 2a. This is also in agreement with the observed values of quantum yields. Molecular orbital analysis along the triplet potential energy surface scan for Ru-N(co-ligand) bond stretching suggests that the lower energy singly occupied molecular orbital (SOMO1) of (MLCT)-M-3, comprised of a d pi orbital of Ru with little contribution of pi orbital of the co-ligand, does not change much when Ru-N bond stretches to reach (MC)-M-3. The higher-energy SOMO2 of the (MLCT)-M-3 state is mostly phenanthroline based pi* orbital. Upon stretching the Ru-N distance, the pi* orbital of phenanthroline in the (MLCT)-M-3 state and d sigma* orbital of the dissociative (MC)-M-3 state are seen to be mixing in an antibonding fashion especially after transition state ((TS)-T-3). This mixing of the d sigma* orbital with the pi* orbital is one of the important factors favoring the release of the N-heterocyclic co-ligand to give photodissociation products.
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