期刊
GREEN CHEMISTRY
卷 23, 期 6, 页码 2362-2371出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc00241d
关键词
-
资金
- Kempe foundation in Sweden
- Carl Tryggers Stifelse [18:175]
- National Natural Science Foundation of China [21838010]
Efficient enzymatic conversion of CO2 to methanol is achieved by encapsulating enzymes in ZIF-8 and coupling with electrocatalytic NADH regeneration, leading to increased methanol concentration and cost reduction.
Efficient enzymatic conversion of CO2 to methanol is limited by low CO2 solubility in water (33 mM), and the high-cost of the cofactor (NADH) hinders the potential large-scale application of CO2 enzymatic conversion. In this study, a bioelectrocatalytic system was established for tackling both these issues, and in this system enzymes were embedded in the metal-organic framework ZIF-8 via in situ encapsulation to increase the substrate (CO2) concentration and pre-concentrate NADH, and a Rh complex-grafted electrode was developed for regenerating NADH in a sustainable manner. The results showed that after encapsulation of enzymes in ZIF-8, the methanol concentration increased from 0.061 to 0.320 mM (5 fold) in three hours. Furthermore, after coupling with electrocatalytic NADH regeneration, the methanol concentration further increased to 0.742 mM (12 fold) compared to a free enzyme system. Overall, methanol was produced at a rate of 822 mu mol g(-1) h(-1).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据