期刊
FOOD CHEMISTRY
卷 221, 期 -, 页码 1797-1804出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2016.10.101
关键词
Acrylamide; Magnetic nanoparticles; Graphene oxide; Dummy surface molecular imprinting
资金
- National Natural Science Foundation of China [21667018, 31660482]
- National Key Technology Research and Development Program of the Ministry of Science and Technology of China [2013BAD19B02]
- Graduate student innovation fund of Jiangxi Province [YC2016-B013]
Novel nano-sized dummy-surface molecularly imprinted polymers (DSMIPs) on a magnetic graphene oxide (GO-Fe3O4) surface were developed as substrates, using propionamide as a dummy template molecule for the selective recognition and rapid pre-concentration and removal of acrylamide (AM) from food samples. These products showed rapid kinetics, high binding capacity (adsorption at 3.68 mg.g(-1)), and selectivity (imprinting factor a 2.83); the adsorption processes followed the Langmuir-Freundlich isotherm and pseudo-second-order kinetic models. Excellent recognition selectivity toward acrylamide was achieved compared to structural analogs, such as propionic and acrylic acids (selectivity factor beta 2.33, and 2.20, respectively). Moreover, DSMIPs-GO-Fe3O4 was used to quantify acrylamide in food samples, yielding satisfactory recovery (86.7-94.3%) and low relative standard deviation (< 4.85%). Thus, our DSMIPs-GO-Fe3O4-based procedure was demonstrated to be a convenient and practical method for the separation, enrichment, and removal of acrylamide from food samples. (C) 2016 Elsevier Ltd. All rights reserved.
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