期刊
DALTON TRANSACTIONS
卷 50, 期 20, 页码 7056-7064出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt00708d
关键词
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资金
- European Research Council (ERC) under the European Union [ERC-724981]
- Spanish Government, Ministerio de Ciencia e Innovacion [CTQ2017-83632, CTQ2015-68370-P, PGC2018-098630-B-I00, MAT2016-77852-C2-1-R, CTQ2016-75150-R, PGC2018-098630B-I00, PGC2018-102047-B-I00]
- Spanish Government, Ministerio de Ciencia e Innovacion (Ramon y Cajal grant) [RYC-2017-22910]
- Generalitat de Catalunya [2017SGR1277]
- ANID, Fondecyt Regular Project [1201962, 1161775]
- Severo Ochoa program for Centres of Excellence in R&D under the FUNMAT-FIP-2016 fellowship [SEV-2015-0496]
- Office of Science, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-AC0205CH11231]
A new heteroditopic ligand, 3pyCCMoid, was presented and used to create novel coordination polymers with Zn-II centers exhibiting different structures and dimensionalities. The study focused on analyzing the impact of synthetic methods and reaction conditions on the formation of final materials, with a special emphasis on the characterization of 2D materials and their stability in water.
We present a new heteroditopic ligand (3pyCCMoid) that contains the typical skeleton of a curcuminoid (CCMoid) decorated with two 3-pyridyl groups. The coordination of 3pyCCMoid with Zn-II centres results in a set of novel coordination polymers (CPs) that display different architectures and dimensionalities (from 1D to 3D). Our work analyses how synthetic methods and slight changes in the reaction conditions affect the formation of the final materials. Great efforts have been devoted toward understanding the coordination entities that provide high dimensional systems, with emphasis on the characterization of 2D materials, including analyses of different types of substrates, stability and exfoliation in water. Here, we foresee the great use of CCMoids in the field of CPs and emphasize 3pyCCMoid as a new-born linker.
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