期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 9, 期 16, 页码 10120-10134出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta00317h
关键词
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资金
- National Natural Science Foundation of China [31800498, 22078035]
- Natural Science Foundation of Liaoning Province of China [2019-BS-16]
- Open Fund of Jiangsu Provincial Key Laboratory of Pulp and Paper [KL201903]
A strategy for preparing high-performance green nano-scale carbon fibrous materials using biomass has been developed, providing biomass-based carbon materials with good flexibility and energy storage properties. The biomass-based CFs demonstrate good specific capacitance and energy density, while also showing great potential in terms of cycle life and flexibility as free-standing supercapacitors.
The preparation of flexible nano-scale carbon materials with good energy storage properties using biomass is a challenging task. Herein, we developed a simple and efficient strategy for preparing high-performance green nano-scale carbon fibrous materials (CFs). A fractionated process is performed to obtain lignin with different chemical structures, including active chemical groups, branched structure, molecular weight and molecular spatial conformation. The fractionated lignin is phosphatized and mixed with cellulose acetate as a precursor material to prepare green nano-scale CFs by electrospinning. This strategy completely gets rid of the dependence of petroleum-based polymer spinning aids and endows biomass-based carbon materials with complete fibrous morphologies, uniform diameter, large surface area, good flexibility and excellent energy storage properties. The specific capacitance of biomass-based CFs as three-electrode capacitance reaches 363.1 F g(-1). At a power density of 800 W kg(-1), the biomass-based CF supercapacitor device delivers an energy density of 31.2 W h kg(-1). Furthermore, the biomass-based CFs exhibit great potential for flexible free-standing supercapacitor with capacitance retention of similar to 98% after 10 000 cycles.
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