期刊
GREEN SYNTHESIS AND CATALYSIS
卷 2, 期 2, 页码 145-155出版社
KEAI PUBLISHING LTD
DOI: 10.1016/j.gresc.2021.04.003
关键词
Radical reaction; Decyanative; Alkylation; Cyano(hetero)arenes; Photochemistry
资金
- Province Science and Technology Project [20204BCJ23010, 20202ACBL216017]
- National Natural Science Foundation of China [21762030, 51878326, 21625203, 21871126, 21901100]
- Jiangxi
The article summarizes recent advances in the radical-mediated decyanative alkylation reactions of cyano(hetero)arene via photo/electrochemistry, discussing the mechanisms involved in cleaving C(sp3)-H, C(sp2)-H, C-C or C-hetero bonds and forming new C-C bonds.
Substituted pyridines are very important skeleton in natural products, agrochemicals and pharmaceuticals, which not only can be used to synthesis chiral ligands and functional materials but also as building blocks in the construction of new photo- or electrochemical properties. As a result, much efforts have been developed towards the synthesis of such compounds. Given the great influence of these synthesis methodologies in organic chemistry, we summarize recent progress of the radical-mediated decyanative alkylation reactions of cyano(hetero)arene via photo/electrochemistry via a radical pathway, in which C(sp3)-H, C(sp2)-H, C-C or C-hetero bonds are cleavaged and a new C-C bond is formed. We also discussed the mechanisms of these radical decyanative alkylation reactions.
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