4.7 Article

Helical carbon nanofibers modified with Fe2O3 as a high performance anode material for lithium-ion batteries

期刊

DALTON TRANSACTIONS
卷 50, 期 17, 页码 5819-5827

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt00275a

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资金

  1. Scientific and Technical Project of Sichuan Province [2019YJ0479, 2019YFG0072]
  2. Postgraduate Innovation Fund Project of Sichuan University of Science and Engineering [y2019025]

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Fe2O3/HCNFs, modified with a particle size of 10-20 nm, demonstrated excellent performance as a novel anode material for lithium-ion batteries, with a capacity of 816.3 mA h g(-1) after 100 cycles at a current density of 200 mA g(-1). This superior performance and easy preparation method highlight the potential of Fe2O3/HCNFs for LIB applications.
Helical carbon nanofibers (HCNFs) modified with Fe2O3 (Fe2O3/HCNFs) with a particle size of about 10-20 nm were first introduced for potential use as a novel anode material for lithium-ion batteries (LIBs). Fe2O3/HCNFs were successfully prepared via a chemical liquid deposition (CLPD) method in this study. HCNFs with a special three-dimensional helical structure improve the conductivity and also provide a strong supporting network space for stress and strain during the volume expansion of Fe2O3 nanoparticles. The Fe2O3/HCNF anode still retains its capacity of 816.3 mA h g(-1) after 100 cycles at the current density of 200 mA g(-1), which is significantly better than those of contrast samples (only 144.2 mA h g(-1) for the bare Fe2O3, 241.2 mA h g(-1) for HCNFs and 486.4 mA h g(-1) for Fe2O3-HCNFs). These superior properties and facile preparation represent the potential of Fe2O3/HCNF anode materials for LIB application.

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