期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 9, 期 17, 页码 10714-10721出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta00715g
关键词
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资金
- NSFC [22025501, 21872038, 21733003, 51773042, 51973040]
- National Key R&D Program of China [2020YFB1505803, 2017YFA0207303]
- Foshan Science and Technology Innovation Program [2017IT100121]
By designing a unique mesoporous MoS2@graphene van der Waals superstructure, high-rate and long-life sodium storage has been achieved, potentially offering a new approach for the future development of sodium-ion batteries.
Transition metal dichalcogenides (TMDs) are promising anode materials for sodium-ion batteries (SIBs), but suffer from low rate capability and poor cycling stability. Here, we describe our efforts in designing a unique MoS2-based van der Waals (vdW) superstructure, namely mesoporous MoS2@graphene supraparticles, for realizing unprecedented high-rate, long-life sodium storage. The key to obtaining mesoporous MoS2@graphene vdW supraparticles is the high mass loading of the initially hydrophilic (NH4)(2)MoS4 precursor into the hydrophobic mesoporous graphene, which is realized through a novel phase-transfer assisted method. Subsequent precursor decomposition confined in similar to 11 nm mesopores triggers the epitaxial growth of MoS2 nanosheets featuring a spherically curved geometry and an expanded interlayer spacing. Thanks to the greatly improved electron and ion transport properties enabled by the unique mesoporous vdW superstructure, the resulting MoS2@graphene vdW supraparticles exhibit arguably the best rate performance ever reported.
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